{"authors":[{"id":"orcid_______::1409f7205efeec06edceb9bd6f653d94","fullName":"Yarur Villanueva, Francisco","name":"Francisco","surname":"Yarur Villanueva","rank":1,"pid":{"id":{"scheme":"orcid","value":"0000-0003-1102-3382"},"provenance":null}},{"id":"orcid_______::b80bd62a38f0e33dd7494e3e5b01513a","fullName":"Quezada Novoa, Victor","name":"Victor","surname":"Quezada Novoa","rank":2,"pid":{"id":{"scheme":"orcid","value":"0000-0001-8360-9847"},"provenance":null}},{"id":null,"fullName":"Rusch, Pascal","name":"Pascal","surname":"Rusch","rank":3,"pid":null},{"id":null,"fullName":"Toso, Stefano","name":"Stefano","surname":"Toso","rank":4,"pid":null},{"id":null,"fullName":"Terban, Maxwell W.","name":"Maxwell W.","surname":"Terban","rank":5,"pid":null},{"id":null,"fullName":"Ivanov, Yurii P.","name":"Yurii P.","surname":"Ivanov","rank":6,"pid":null},{"id":null,"fullName":"Chu, Joaquin Carlos","name":"Joaquin Carlos","surname":"Chu","rank":7,"pid":null},{"id":null,"fullName":"Kirshenbaum, Maxine J.","name":"Maxine J.","surname":"Kirshenbaum","rank":8,"pid":null},{"id":null,"fullName":"Nikbin, Ehsan","name":"Ehsan","surname":"Nikbin","rank":9,"pid":null},{"id":"orcid_______::3724a384f54cf12365c59d289b58f007","fullName":"Gendron Romero, Maria J.","name":"Maria J.","surname":"Gendron Romero","rank":10,"pid":{"id":{"scheme":"orcid","value":"0009-0003-2199-5107"},"provenance":null}},{"id":null,"fullName":"Prato, Mirko","name":"Mirko","surname":"Prato","rank":11,"pid":{"id":{"scheme":"orcid_pending","value":"0000-0002-2188-8059"},"provenance":null}},{"id":null,"fullName":"Divitini, Giorgio","name":"Giorgio","surname":"Divitini","rank":12,"pid":{"id":{"scheme":"orcid_pending","value":"0000-0003-2775-610x"},"provenance":null}},{"id":null,"fullName":"Howe, Jane Y.","name":"Jane Y.","surname":"Howe","rank":13,"pid":{"id":{"scheme":"orcid_pending","value":"0000-0001-9319-3988"},"provenance":null}},{"id":null,"fullName":"Wilson, Mark W. B.","name":"Mark W. B.","surname":"Wilson","rank":14,"pid":{"id":{"scheme":"orcid_pending","value":"0000-0002-1957-2979"},"provenance":null}},{"id":null,"fullName":"Manna, Liberato","name":"Liberato","surname":"Manna","rank":15,"pid":{"id":{"scheme":"orcid_pending","value":"0000-0003-4386-7985"},"provenance":null}}],"openAccessColor":"hybrid","publiclyFunded":false,"eoscIfGuidelines":null,"type":"publication","language":{"code":"eng","label":"English"},"countries":null,"subjects":[{"subject":{"scheme":"keyword","value":"Materials Science"},"provenance":null},{"subject":{"scheme":"keyword","value":"Materials Science (cond-mat.mtrl-sci)"},"provenance":null},{"subject":{"scheme":"keyword","value":"FOS: Physical sciences"},"provenance":null},{"subject":{"scheme":"FOS","value":"02 engineering and technology"},"provenance":null},{"subject":{"scheme":"FOS","value":"0210 nano-technology"},"provenance":null},{"subject":{"scheme":"keyword","value":"Article"},"provenance":null}],"mainTitle":"Synthesis and Structural Analysis of an Emissive Colloidal Argyrodite Nanocrystal: Canfieldite Ag<sub>8</sub>SnS<sub>6</sub>","subTitle":null,"descriptions":["We resolve a phase identification controversy in the Ag-Sn-S material system by unraveling the polymorphic structure of nanocrystals within the argyrodite material family. Argyrodites are a class of superionic materials used in their bulk form for applications in solid-state batteries and thermoelectrics, where their advantageous properties relate to their polymorphism. However, despite their well-studied bulk applications, the limited exploration at the nanoscale has left considerable potential for the discovery of emerging properties due to size effects. Further, phase identification presents a prominent challenge to the study of polymorphs in superionic conductors and related mate-rials. In this work, we synthesize canfieldite-like (Ag8SnS6) nanocrystals to understand their formation and structural behavior at the nanoscale. We observe the emergence of emissive, meta-stable, cluster-like species. Then, high-resolution transmission electron microscopy reveals indistinguishable polymorphs of canfieldite due to identical heavy-atom frameworks. However, using synchrotron X-ray total scattering for pair distribution function analysis, we uncover structural distortions, showing a pseudo-orthorhombic configuration that likely gives rise to the red emission. Further, we investigate the optical properties and structure of Ag8SnS6 nanocrystals upon the addition of Zn2+, the cation of interest in the canfieldite vs. pirquitasite (Ag2ZnSnS4) phase identification controversy. We show that Zn2+ is incorporated in the canfieldite-like structure through the replacement of Ag+, boosting the emission. Our results solve a standing phase identification challenge and uncover fundamental insights for the synthesis and structure of canfieldite nanocrystals, laying the ground for the exploration of other argyrodite materials with emerging properties at the nanoscale.","28 pages, 23 figures"],"publicationDate":"2025-07-30","publisher":"American Chemical Society (ACS)","embargoEndDate":"2026-02-01","sources":["Crossref","J Am Chem Soc"],"formats":null,"contributors":null,"coverages":null,"bestAccessRight":{"code":"c_abf2","label":"OPEN","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/"},"container":{"name":"Journal of the American Chemical Society","issnPrinted":"0002-7863","issnOnline":"1520-5126","issnLinking":null,"ep":"29422","iss":null,"sp":"29413","vol":"147","edition":null,"conferencePlace":null,"conferenceDate":null},"documentationUrls":null,"codeRepositoryUrl":null,"programmingLanguage":null,"contactPeople":null,"contactGroups":null,"tools":null,"size":null,"version":null,"geoLocations":null,"id":"doi_dedup___::1c879bbbca2bb89d31e1abea4f43ec94","originalIds":["10.1021/jacs.5c09495","50|doiboost____|1c879bbbca2bb89d31e1abea4f43ec94","50|datacite____::fa143e71cde9c8730795c70f4cba4e97","10.48550/arxiv.2602.24114","od_______267::428e4de90ebde2e3ea39cd66f35df365","40735903","PMC12356587","50|od_______267::428e4de90ebde2e3ea39cd66f35df365","oai:pubmedcentral.nih.gov:12356587","50|od________18::f72c8d7f021bc59ec6f7c274bb41644d","oai:arXiv.org:2602.24114","50|sygma_______::1c879bbbca2bb89d31e1abea4f43ec94"],"pids":[{"scheme":"doi","value":"10.1021/jacs.5c09495"},{"scheme":"doi","value":"10.48550/arxiv.2602.24114"},{"scheme":"pmid","value":"40735903"},{"scheme":"pmc","value":"PMC12356587"},{"scheme":"arXiv","value":"2602.24114"}],"dateOfCollection":null,"lastUpdateTimeStamp":null,"indicators":{"citationImpact":{"citationCount":2.0,"influence":2.2321918E-9,"popularity":3.533256E-9,"impulse":2.0,"citationClass":"C5","influenceClass":"C5","impulseClass":"C5","popularityClass":"C4"}},"projects":[{"id":"nserc_______::1e5e62235d094afd01cd56e65112fc63","code":"unidentified","acronym":null,"title":"unidentified","funder":"Natural Sciences and Engineering Research Council of Canada","pids":null},{"id":"corda__h2020::c7b42ef529e8c34ba8a8051fff0a6f87","code":"870313","acronym":"STREAMLINE","title":"Sustainable research at micro and nano X-ray beamlines","funder":"European Commission","pids":[{"scheme":"doi","value":"10.3030/870313"}]},{"id":"corda_____he::71aa6d946ac17b08430d9d03d219084d","code":"101131111","acronym":"DELIGHT","title":"Designing of multifunctional nanomaterials for light-driven innovation technologies","funder":"European Commission","pids":[{"scheme":"doi","value":"10.3030/101131111"}]}],"organizations":[{"legalName":"Institut National des Sciences Appliquées de Lyon","acronym":"INSA","id":"openorgs____::6e23b6f3a5f9768d19cc49c0ff176f47","pids":[{"scheme":"wikidata","value":"Q1633859"},{"scheme":"ISNI","value":"0000000417655089"},{"scheme":"Wikidata","value":"Q1633859"},{"scheme":"ROR","value":"https://ror.org/050jn9y42"},{"scheme":"FundRef","value":"501100009081"},{"scheme":"PIC","value":"999886089"},{"scheme":"GRID","value":"grid.15399.37"},{"scheme":"fundref","value":"501100009081"},{"scheme":"OrgRef","value":"10828425"}],"countries":[{"code":"FR","label":"France"}],"websiteurl":"http://www.insa-lyon.fr/"},{"legalName":"Italian Institute of Technology","acronym":"Italian Institute of Technology","id":"openorgs____::9969a66abab9c1681637223876e5d1d2","pids":[{"scheme":"fundref","value":"501100009531"},{"scheme":"ROR","value":"https://ror.org/042t93s57"},{"scheme":"GRID","value":"grid.25786.3e"},{"scheme":"OrgReg","value":"IT4022"},{"scheme":"wikidata","value":"Q3803623"},{"scheme":"Wikidata","value":"Q3803623"},{"scheme":"FundRef","value":"501100009531"},{"scheme":"mag_id","value":"30771326"},{"scheme":"ISNI","value":"0000000417642907"},{"scheme":"OrgRef","value":"19970839"},{"scheme":"Wikidata","value":"Q39902232"}],"countries":[{"code":"IT","label":"Italy"}],"websiteurl":"https://www.iit.it/"},{"legalName":"University of Toronto","acronym":"UofT","id":"openorgs____::1ba76e2ce1d7d529a66c628d877a593b","pids":[{"scheme":"FundRef","value":"501100000181"},{"scheme":"OrgRef","value":"221783"},{"scheme":"ROR","value":"https://ror.org/03dbr7087"},{"scheme":"fundref","value":"501100003579"},{"scheme":"GRID","value":"grid.17063.33"},{"scheme":"FundRef","value":"100008386"},{"scheme":"fundref","value":"501100007921"},{"scheme":"fundref","value":"501100002827"},{"scheme":"OrgRef","value":"251833"},{"scheme":"fundref","value":"501100008097"},{"scheme":"fundref","value":"501100000064"},{"scheme":"Wikidata","value":"Q3551675"},{"scheme":"ROR","value":"https://ror.org/04s5mat29"},{"scheme":"wikidata","value":"Q3551675"},{"scheme":"OrgRef","value":"599409"},{"scheme":"FundRef","value":"501100003579"},{"scheme":"FundRef","value":"501100004730"},{"scheme":"wikidata","value":"Q180865"},{"scheme":"FundRef","value":"501100022101"},{"scheme":"fundref","value":"501100000181"},{"scheme":"OrgRef","value":"333619"},{"scheme":"Wikidata","value":"Q180865"},{"scheme":"OrgRef","value":"5303285"},{"scheme":"OrgRef","value":"32774"},{"scheme":"fundref","value":"501100006151"},{"scheme":"FundRef","value":"501100003474"},{"scheme":"fundref","value":"501100002323"},{"scheme":"fundref","value":"501100022101"},{"scheme":"FundRef","value":"501100008097"},{"scheme":"PIC","value":"986196188"},{"scheme":"FundRef","value":"501100002323"},{"scheme":"fundref","value":"501100000154"},{"scheme":"FundRef","value":"501100002827"},{"scheme":"fundref","value":"501100004730"},{"scheme":"Wikidata","value":"Q6120110"},{"scheme":"wikidata","value":"Q6120110"},{"scheme":"FundRef","value":"501100000064"},{"scheme":"fundref","value":"100008386"},{"scheme":"FundRef","value":"501100007921"},{"scheme":"FundRef","value":"501100007224"},{"scheme":"FundRef","value":"501100000086"},{"scheme":"RRID","value":"RRID:nlx_15536"},{"scheme":"mag_id","value":"185261750"},{"scheme":"OrgRef","value":"358828"},{"scheme":"OrgRef","value":"1724690"},{"scheme":"FundRef","value":"100009036"},{"scheme":"ISNI","value":"0000000121572938"},{"scheme":"OrgRef","value":"7955325"},{"scheme":"RRID","value":"RRID:SCR_011733"},{"scheme":"FundRef","value":"501100006151"},{"scheme":"FundRef","value":"501100000154"},{"scheme":"fundref","value":"501100000086"},{"scheme":"fundref","value":"501100007224"},{"scheme":"fundref","value":"501100003474"},{"scheme":"fundref","value":"501100020895"}],"countries":[{"code":"CA","label":"Canada"}],"websiteurl":"https://www.utoronto.ca/"},{"legalName":"Concordia University","acronym":"Concordia University","id":"openorgs____::1f4314a88271f69682248c29b5bbd1e9","pids":[{"scheme":"ROR","value":"https://ror.org/04dwckp88"},{"scheme":"fundref","value":"501100002914"},{"scheme":"GRID","value":"grid.410319.e"},{"scheme":"FundRef","value":"501100002914"},{"scheme":"OrgRef","value":"42914"},{"scheme":"Wikidata","value":"Q326342"},{"scheme":"ISNI","value":"0000000419368630"},{"scheme":"PIC","value":"968922622"},{"scheme":"ROR","value":"https://ror.org/0420zvk78"},{"scheme":"wikidata","value":"Q326342"}],"countries":[{"code":"CA","label":"Canada"}],"websiteurl":"https://www.concordia.ca/"},{"legalName":"European Synchrotron Radiation Facility","acronym":"ESRF","id":"openorgs____::5cfee6a53455a10e53237f9e32342538","pids":[{"scheme":"ROR","value":"https://ror.org/02550n020"},{"scheme":"GRID","value":"grid.5398.7"},{"scheme":"mag_id","value":"2801997478"},{"scheme":"PIC","value":"999484121"},{"scheme":"wikidata","value":"Q901751"},{"scheme":"OrgRef","value":"1424678"},{"scheme":"Wikidata","value":"Q901751"},{"scheme":"FundRef","value":"501100001671"},{"scheme":"ISNI","value":"0000000406416373"},{"scheme":"fundref","value":"501100001671"},{"scheme":"OrgReg","value":"INT1002"},{"scheme":"RNSR","value":"RNSR:202123995V"}],"countries":[{"code":"FR","label":"France"}],"websiteurl":"http://www.esrf.eu/"},{"legalName":"Matériaux Ingénierie et Science","acronym":"MATEIS","id":"openorgs____::0f9a54c49e25849e979c0e5d63eb71db","pids":[{"scheme":"wikidata","value":"Q30261510"},{"scheme":"GRID","value":"grid.462614.3"},{"scheme":"ISNI","value":"0000000102922242"},{"scheme":"ROR","value":"https://ror.org/01rnfhz46"},{"scheme":"CNRS","value":"UMR5510"}],"countries":[{"code":"FR","label":"France"}],"websiteurl":"http://mateis.insa-lyon.fr/"}],"communities":[{"code":"uarctic","label":"UArctic","provenance":null}],"collectedFrom":[{"key":"openaire____::9e3be59865b2c1c335d32dae2fe7b254","value":"Datacite"},{"key":"openaire____::a8db6f6b2ce4fe72e8b2314a9a93e7d9","value":"Sygma"},{"key":"openaire____::081b82f96300b6a6e3d282bad31cb6e2","value":"Crossref"},{"key":"opendoar____::8b6dd7db9af49e67306feb59a8bdc52c","value":"Europe PubMed Central"},{"key":"opendoar____::6f4922f45568161a8cdf4ad2299f6d23","value":"arXiv.org e-Print Archive"},{"key":"opendoar____::eda80a3d5b344bc40f3bc04f65b7a357","value":"PubMed Central"}],"instances":[{"pids":[{"scheme":"doi","value":"10.1021/jacs.5c09495"}],"license":"CC BY","accessRight":{"code":"c_abf2","label":"OPEN","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/","openAccessRoute":"hybrid"},"type":"Article","urls":["https://doi.org/10.1021/jacs.5c09495"],"publicationDate":"2025-07-30","refereed":"peerReviewed","hostedBy":{"key":"issn___print::385b2b6af1a402cb580da5616b8059e1","value":"Journal of the American Chemical Society"},"collectedFrom":{"key":"openaire____::081b82f96300b6a6e3d282bad31cb6e2","value":"Crossref"}},{"pids":[{"scheme":"doi","value":"10.48550/arxiv.2602.24114"}],"license":"CC BY NC ND","type":"Article","urls":["https://dx.doi.org/10.48550/arxiv.2602.24114"],"publicationDate":"2026-01-01","refereed":"nonPeerReviewed","hostedBy":{"key":"openaire____::55045bd2a65019fd8e6741a755395c8c","value":"Unknown Repository"},"collectedFrom":{"key":"openaire____::9e3be59865b2c1c335d32dae2fe7b254","value":"Datacite"}},{"pids":[{"scheme":"pmid","value":"40735903"},{"scheme":"pmc","value":"PMC12356587"}],"alternateIdentifiers":[{"scheme":"doi","value":"10.1021/jacs.5c09495"}],"type":"Article","urls":["https://pubmed.ncbi.nlm.nih.gov/40735903"],"refereed":"nonPeerReviewed","hostedBy":{"key":"issn___print::385b2b6af1a402cb580da5616b8059e1","value":"Journal of the American Chemical Society"},"collectedFrom":{"key":"opendoar____::8b6dd7db9af49e67306feb59a8bdc52c","value":"Europe PubMed Central"}},{"alternateIdentifiers":[{"scheme":"doi","value":"10.1021/jacs.5c09495"}],"license":"CC BY","accessRight":{"code":"c_abf2","label":"OPEN","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/","openAccessRoute":null},"type":"Article","urls":["https://pmc.ncbi.nlm.nih.gov/articles/PMC12356587/","https://pubmed.ncbi.nlm.nih.gov/40735903/","https://doi.org/10.1021/jacs.5c09495"],"publicationDate":"2025-07-30","refereed":"nonPeerReviewed","hostedBy":{"key":"opendoar____::eda80a3d5b344bc40f3bc04f65b7a357","value":"PubMed Central"},"collectedFrom":{"key":"opendoar____::eda80a3d5b344bc40f3bc04f65b7a357","value":"PubMed Central"}},{"pids":[{"scheme":"arXiv","value":"2602.24114"}],"alternateIdentifiers":[{"scheme":"doi","value":"10.1021/jacs.5c09495"}],"accessRight":{"code":"c_abf2","label":"OPEN","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/","openAccessRoute":null},"type":"Preprint","urls":["http://arxiv.org/abs/2602.24114"],"publicationDate":"2026-02-27","refereed":"nonPeerReviewed","hostedBy":{"key":"opendoar____::6f4922f45568161a8cdf4ad2299f6d23","value":"arXiv.org e-Print Archive"},"collectedFrom":{"key":"opendoar____::6f4922f45568161a8cdf4ad2299f6d23","value":"arXiv.org e-Print Archive"}},{"alternateIdentifiers":[{"scheme":"doi","value":"10.1021/jacs.5c09495"}],"license":"CC BY","accessRight":{"code":"c_abf2","label":"OPEN","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/","openAccessRoute":null},"type":"Article","urls":["http://dx.doi.org/10.1021/jacs.5c09495"],"refereed":"nonPeerReviewed","hostedBy":{"key":"issn___print::385b2b6af1a402cb580da5616b8059e1","value":"Journal of the American Chemical Society"},"collectedFrom":{"key":"openaire____::a8db6f6b2ce4fe72e8b2314a9a93e7d9","value":"Sygma"}}],"links":[{"header":{"relationType":"resultProject","relationClass":"isProducedBy","relatedIdentifier":"nserc_______::1e5e62235d094afd01cd56e65112fc63","relatedRecordType":"project","relationProvenance":"sysimport:actionset","trust":"0.91"},"collectedfrom":[{"dsId":"openaire____::5bf85b5b3a20d717bb4dc647c51ca600","dsName":"Natural Sciences and Engineering Research Council of Canada"}],"projectTitle":"unidentified","code":"unidentified","funding":{"funder":{"id":"nserc_______::NSERC","shortname":"NSERC","name":"Natural Sciences and Engineering Research Council of Canada","jurisdiction":{"code":"CA","label":"Canada"},"pid":null},"level0":{"id":null,"description":null,"name":null},"level1":{"id":null,"description":null,"name":null},"level2":{"id":null,"description":null,"name":null}}},{"header":{"relationType":"resultProject","relationClass":"isProducedBy","relatedIdentifier":"corda__h2020::c7b42ef529e8c34ba8a8051fff0a6f87","relatedRecordType":"project","relationProvenance":"iis","trust":"0.897"},"collectedfrom":[{"dsId":"openaire____::a55eb91348674d853191f4f4fd73d078","dsName":"CORDA - COmmon Research DAta Warehouse - Horizon 2020"}],"projectTitle":"Sustainable research at micro and nano X-ray beamlines","code":"870313","funding":{"funder":{"id":"ec__________::EC","shortname":"EC","name":"European Commission","jurisdiction":{"code":"EU","label":"European Union"},"pid":null},"level0":{"id":"ec__________::EC::H2020","description":"Horizon 2020 Framework Programme","name":"H2020"},"level1":{"id":"ec__________::EC::H2020::RIA","description":"Research and Innovation action","name":"RIA"},"level2":{"id":null,"description":null,"name":null}},"startDate":"2019-11-15","endDate":"2024-05-14"},{"header":{"relationType":"resultProject","relationClass":"isProducedBy","relatedIdentifier":"corda_____he::71aa6d946ac17b08430d9d03d219084d","relatedRecordType":"project","relationProvenance":"sysimport:crosswalk","trust":"0.9"},"collectedfrom":[{"dsId":"openaire____::3f264f93cf3b0cfc4ede188a6300455c","dsName":"CORDA - COmmon Research DAta Warehouse - Horizon Europe"}],"projectTitle":"Designing of multifunctional nanomaterials for light-driven innovation technologies","code":"101131111","funding":{"funder":{"id":"ec__________::EC","shortname":"EC","name":"European Commission","jurisdiction":{"code":"EU","label":"European Union"},"pid":null},"level0":{"id":"ec__________::EC::HE","description":"Horizon Europe Framework Programme","name":"HE"},"level1":{"id":"ec__________::EC::HE::HORIZON-TMA-MSCA-SE","description":"HORIZON TMA MSCA Staff Exchanges","name":"HORIZON-TMA-MSCA-SE"},"level2":{"id":null,"description":null,"name":null}},"startDate":"2024-01-01","endDate":"2027-12-31"}],"otherTitles":null,"green":true,"inDiamondJournal":false,"isGreen":true,"isInDiamondJournal":false}